Tlusty, Tsvi
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
All known life forms are based upon a hierarchy of interwoven feedback loops, operating over a cascade of space, time and energy scales. Among the most basic loops are those connecting DNA and proteins. For example, in genetic networks, DNA genes are expressed as proteins, which may bind near the same genes and thereby control their own expression....
Santos-Carballal, David Roldan, Alberto Dzade, Nelson Y de Leeuw, Nora H
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
The growing environmental, industrial and commercial interests in understanding the processes of carbon dioxide (CO2) capture and conversion have led us to simulate, by means of density functional theory calculations, the application of different iron oxide and sulfide minerals to capture, activate and catalytically dissociate this molecule. We hav...
Beale, Andrew M Jacques, Simon D M Di Michiel, Marco Mosselmans, J Frederick W Price, Stephen W T Senecal, Pierre Vamvakeros, Antonios Paterson, James
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
The imaging of catalysts and other functional materials under reaction conditions has advanced significantly in recent years. The combination of the computed tomography (CT) approach with methods such as X-ray diffraction (XRD), X-ray fluorescence (XRF) and X-ray absorption near-edge spectroscopy (XANES) now enables local chemical and physical stat...
Gholami, Rahman Stere, Cristina E Goguet, Alexandre Hardacre, Christopher
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
The combination of non-thermal plasma (NTP) with catalyst systems as an alternative technology to remove NOx emissions in the exhaust of lean-burn stationary and mobile sources is reviewed. Several factors, such as low exhaust gas temperatures (below 300°C), low selectivity to N2 and the presence of impurities, make current thermally activated tech...
Tosoni, Sergio Chen, Hsin-Yi Tiffany Ruiz Puigdollers, Antonio Pacchioni, Gianfranco
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
Biomass refers to plant-based materials that are not used for food or feed. As an energy source, lignocellulosic biomass (lignin, cellulose and hemicellulose) can be converted into various forms of biofuel using thermal, chemical and biochemical methods. Chemical conversion implies the use of solid catalysts, usually oxide materials. In this contex...
Stößer, T Chen, T T D Zhu, Y Williams, C K
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
A 'Switch' catalysis method is reviewed whereby a single catalyst is switched between ring-opening polymerization and ring-opening copolymerization cycles. It allows the efficient synthesis of block copolymers from mixtures of lactones, epoxides, anhydrides and carbon dioxide. In order to use and further develop such 'Switch' catalysis, it is impor...
Khan, Zainab Dummer, Nicholas F Edwards, Jennifer K
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
A series of bimetallic silver-palladium catalysts supported on titania were prepared by wet impregnation and assessed for the direct synthesis of hydrogen peroxide, and its subsequent side reactions. The addition of silver to a palladium catalyst was found to significantly decrease hydrogen peroxide productivity and hydrogenation, but crucially inc...
Hutchings, Graham J Catlow, C Richard Turner, Nicholas J
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
Palkovits, Regina Delidovich, Irina
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
Renewable carbon feedstocks such as biomass and CO2 present an important element of future circular economy. Especially biomass as highly functionalized feedstock provides manifold opportunities for the transformation into attractive platform chemicals. However, this change of the resources requires a paradigm shift in refinery design. Fossil feeds...
Garner, Dave
Published in
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
