Mchiri, Chadlia Edziri, Hayet Hajji, Halima Bouachrine, Mohammed Acherar, Samir Frochot, Céline Eldine, Hanan O Badr Moussa, Sana Ben Nasri, Habib
Published in
Journal of Chemical Sciences
The reaction of the [meso-tetra(p-chlorophenyl)porphyrinato]cadmium(II) complex ([Cd(TClPP)]) with an excess of 2-aminopyridine results in the formation of the corresponding axially ligated (2- aminopyridine)[meso-tetra(p-chlorophenyl)porphyrinato]cadmium(II)with the formula [Cd(TClPP)(2-NH2Py)] (I). This five-coordinated metalloporphyrin was chara...
Isaev, Alexander N
Published in
Journal of Chemical Sciences
Using the MP2/aug-cc-pVTZ method, quantum chemical calculations of binary complexes with intermolecular C(sp3)...Hal−M (Hal = F, Cl, Br; M = Li, Na, Cu, Mg) bonds formed by the methide anion and its derivatives with metal halides were carried out. The calculations showed that the binding energy in the carbanion complex is higher, the greater the di...
Feng, Yuqin Yang, Ming Zhang, Yanbo Liu, Hongjun Ju, Haiyan Zhang, Gang Ma, Wenxia Wu, Yaqi Yu, Yunzi Yang, Yongsheng
...
Published in
Journal of Chemical Sciences
AbstractEnergy-saving smart windows could reduce building energy consumption by dynamically regulating solar transmission without consuming additional energy. However, current thermochromic smart windows based on hydroxypropyl cellulose (HPC) are still facing challenges, such as low durability and unsatisfactory in regulating the solar infrared reg...
Chowdhury, Abhinanda Singh, Prashant Chandra
Published in
Journal of Chemical Sciences
AbstractThe conformational state and noncovalent interaction of protonated dopamine (p-dopamine) play an important role in its key and lock binding with its receptors. Hence, understanding of the role of weak noncovalent interactions in the stability of the higher order structures of the p-dopamine is desired. In this study, we have combined the sp...
Zhang, Lin Zheng, Jun Zeng, Zhishu Luo, Guangyan Li, Xiaoyue Zhang, Qianjun
Published in
Journal of Chemical Sciences
In this study, cucurbit[8]uril (Q[8]) was used as a carrier for Sulfanilamide (G1) and sulfamethoxazole (G2), and the crystals of their inclusion complexes were cultured in a 3M HCl aqueous solution upon the addition of ZnCl2 as an inducer. The crystal structure was characterized using single-crystal X-ray diffraction. The results showed that two n...
Sadegh Hassani, Sedigheh Samiee, Leila Rashidi, Alimorad Ganjali, Mohammad Reza
Published in
Journal of Chemical Sciences
In this work, various methods (chemical vapor deposition (CVD), hydrothermal, and pyrolysis) have been applied for preparing sulfur–nitrogen co-doped porous graphene. Afterwards, the electrochemical behavior of the samples prepared through different techniques was investigated for oxygen reduction reaction (ORR). The prepared heteroatoms-doped elec...
Nongpiur, Carley Giffert L Tripathi, Deepak Kumar Poluri, Krishna Mohan Rawat, Hemant Kollipara, Mohan Rao
Published in
Journal of Chemical Sciences
Reaction of [(arene)MCl2]2 with bidentate 4, 5-diazafluorene-9-one (dafo) and derived Schiff-base ligands (L1–L3) in the presence of ammonium hexafluorophosphate yielded mononuclear cationic complexes having general formula [(arene)MLCl]PF6 {M = Ru, arene = benzene (1, 5, 9); M = Ru, arene = p-cymene (4, 8); M = Rh, arene = Cp* (2, 6, 10); M = Ir, ...
Ul Lah, Hafiz Mir, Shabir Ahmad Hussain, Gulzar Wani, Rafiq Ahmad Yousuf, Syed Khalid
Published in
Journal of Chemical Sciences
A highly chemo- and diastereoselective vic-dibromination of olefins has been developed. The process employs a readily available N-Bromosuccinimide (NBS)/DMSO reagent system as a bromine source. High substrate scope, simple reaction conditions, application to natural products and glycals makes the process very attractive.Graphical abstractA highly c...
KARUEHANON, WEEANUCH FUNFUENHA, WATCHAREE PHUTTAWONG, NATTAPORN
Published in
Journal of Chemical Sciences
Molecularly imprinted polymers of triphenylphosphine oxide (MIPs-TPPO) were synthesized and evaluated for use as a solid scavenger to remove triphenylphosphine oxide from reaction mixtures, a byproduct commonly formed during organic synthesis reactions involving triphenylphosphine (PPh3) reagent. The efficiency of synthesized polymers was initially...
Naik, M Z Rodrigues, L Torney, P S Salker, A V
Published in
Journal of Chemical Sciences
Pristine and indium doped magnesium ferrite nanoparticles have been prepared by the sol-gel method. The phase formation has been confirmed from XRD (X-ray diffraction) whereas nanosize has been displayed through TEM (Transmission Electron Microscope) images. BET (Brunauer–Emmett–Teller) analysis showed an increase in surface area for the indium dop...