Zhu, Haojie Wang, Fangcheng Peng, Lu Win, Tingting Kang, Feiyu Yang, Cheng
Published in
Angewandte Chemie (International ed. in English)
Rechargeable aqueous sodium ion batteries (ASIBs) are rising as an important alternative to lithium ion batteries, owing to their safety and low cost. Metal anodes show a high theoretical capacity and nonselective hydrated ion insertion for ASIBs, yet their large volume expansion and sluggish reaction kinetics resulted in poor electrochemical stabi...
Thaggard, Grace C Leith, Gabrielle A Sosnin, Daniil Martin, Corey R Park, Kyoung Chul McBride, Margaret K Lim, Jaewoong Yarbrough, Brandon J Maldeni Kankanamalage, Buddhima K P Wilson, Gina R
...
Published in
Angewandte Chemie (International ed. in English)
Confinement-imposed photophysics was probed for novel stimuli-responsive hydrazone-based compounds demonstrating a conceptual difference in their behavior within 2D versus 3D porous matrices for the first time. The challenges associated with photoswitch isomerization arising from host interactions with photochromic compounds in 2D scaffolds could b...
Zhang, Youzi Guo, Peng Guo, Shaohui Xin, Xu Wang, Yijin Huang, Wenjing Wang, Maohuai Yang, Bowen Sobrido, Ana Jorge Ghasemi, Jahan B
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Published in
Angewandte Chemie (International ed. in English)
An optimized approach to producing lattice-matched heterointerfaces for electrocatalytic hydrogen evolution has not yet been reported. Herein, we present the synthesis of lattice-matched Mo2C-Mo2N heterostructures using a gradient heating epitaxial growth method. The well lattice-matched heterointerface of Mo2C-Mo2N generating near-zero hydrogen ad...
Parastar, Hadi Tauler, Roma
Published in
Angewandte Chemie (International ed. in English)
This Review summarizes how big (bio)chemical data (BBCD) can be analyzed with multivariate chemometric methods and highlights some of the important challenges faced by modern analytical researches. Here, the potential of chemometric methods to solve BBCD problems that are being encountered in chromatographic, spectroscopic and hyperspectral imaging...
Jahnke, Wolfgang Paladini, Johannes Habazettl, Judith M Wiget, Andrea Loo, Alice Cowan Jacob, Sandra W Grzesiek, Stephan Manley, Paul W
Published in
Angewandte Chemie (International ed. in English)
Soellner published on the interplay between allosteric and adenosine triphosphate (ATP)-competitive inhibitors of ABL kinase, showing that the latter preferably binds to different conformational states of ABL compared to allosteric agents that specifically target the ABL myristate pocket (STAMP) and deducing that asciminib cannot bind to ABL simult...
Wagner, Nicolai Stephan, Milena Höglinger, Doris Nadler, André
Published in
Angewandte Chemie (International ed. in English)
Lipid messengers exert their function on short time scales at distinct subcellular locations, yet most experimental approaches for perturbing their levels trigger cell-wide concentration changes. Herein, we report on a coumarin-based photocaging group that can be modified with organelle-targeting moieties by click chemistry and thus enables photore...
Patra, Tuhin Wirth, Thomas
Published in
Angewandte Chemie (International ed. in English)
Oxidative cleavage of alkenes into carbonyl molecules mainly relies on either ozonolysis or Lemieux-Johnson oxidation involving high valent transition metal oxides. Safety, technical concerns and highly oxidizing conditions of both these procedures limited their adoption in streamlined synthesis. Like ozone, photosensitized nitroarenes can deliver ...
Deng, Qiang Zhou, Rong Zhang, Yong-Chao Li, Xiang Li, Jiahui Tu, Shaobo Sheng, Guan Wang, Jun Zeng, Zheling Yoskamtorn, Tatchamapan
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Published in
Angewandte Chemie (International ed. in English)
Currently, the less favorable C=O hydrogenation and weak concerted acid catalysis cause unsatisfactory catalytic performance in the upgrading biomass-derived furfurals (i.e., furfural, 5-methyl furfural, and 5-hydroxymethyl furfural) to ketones (i.e., cyclopentanone, 2,5-hexanedione, and 1-hydroxyl-2,5-hexanedione). Herein, a series of partial oxid...
Schiene-Fischer, Cordelia Fischer, Gunter Braun, Manfred
Published in
Angewandte Chemie (International ed. in English)
Cyclophilins, enzymes with peptidyl-prolyl cis/trans isomerase activity, are relevant to a large variety of biological processes. The most abundant member of this enzyme family, cyclophilin A, is the cellular receptor of the immunosuppressive drug cyclosporine A (CsA). As a consequence of the pathophysiological role of cyclophilins, particularly in...
Gerdt, Philipp Studer, Armido
Published in
Angewandte Chemie (International ed. in English)
A method for the synthesis of functionalized alternating copolymers by reversible deactivation radical polymerization was developed. Copolymerization by reversible addition-fragmentation chain transfer of hexenyl vinyl ether with a novel fluorinated divinyl monomer yields alternating cyclopolymers that can be chemoselectively modified by three dist...
