Chen, Chun-Hao Liu, Gui-Wang Chen, Xin Deger, Caner Jin, Run-Jun Wang, Kai-Li Chen, Jing Xia, Yu Huang, Lei Yavuz, Ilhan
...
Published in
Angewandte Chemie (International ed. in English)
Inverted (p-i-n) perovskite solar cells (PSCs) have experienced remarkable advancements in recent years, which is largely attributed to the development of novel hole-transport layer (HTL) self-assembled monolayer (SAM) materials. Methoxy (MeO-) groups are typically introduced into SAM materials to enhance their wettability and effectively passivate...
Zhang, Ya-Qun Zhang, Meng Wang, Zilong Bao, Yang-Oujie Wang, Yuqi Tian, Yungang Ye, Lei Ye, Min
Published in
Angewandte Chemie (International ed. in English)
Lanostane-type triterpenoids are important bioactive secondary metabolites of mushrooms, though their biosynthetic study has been challenging due to scattered genes. Herein, the strategies of combining metabolomics and transcriptomics analyses, functional motif blast, and KEGG (Kyoto Encyclopedia of Genes and Genomes) annotation were used to discov...
Xu, Hanren Wang, Qian Qi, Zhen Li, Xianghao Lei, Yifan An, Hongyu Tian, He Qu, Da-Hui
Published in
Angewandte Chemie (International ed. in English)
Supramolecular coordination assemblies play an important role in both material science and biological systems. Despite significant efforts in their development, most existing examples are thermodynamically controlled, which lack the adaptability and autonomy essential for the creation of advanced materials. In this work, we have developed non-equil...
Zhang, Mo Wang, Zifeng Bo, Xin Huang, Rui Deng, Dehui
Published in
Angewandte Chemie (International ed. in English)
Two-dimensional (2D) materials have been utilized broadly in kinds of catalytic reactions due to their fully exposed active sites and special electronic structure. Compared with real catalysts, which are usually bulk or particle, 2D materials have more well-defined structures. With easily identified structure-modulated engineering, 2D materials bec...
Budzelaar, Peter H M Bochmann, Manfred Landrini, Martina Rocchigiani, Luca
Published in
Angewandte Chemie (International ed. in English)
Two recent high-profile publications reported the formation of Heck-type arylated alkenes catalysed by MeDalPhosAuCl/AgOTf (J. Am. Chem. Soc. 2023, 145, 8810) and their cyclisation to tetralines (Angew. Chem. Int. Ed. 2023, e202312786). It was claimed that these were the first demonstrations in gold catalysis of alkene insertion into Au-aryl bonds,...
Tanepau, Joao Bonnaanaa, Hafsa Macé, Angèle Guérin, Arthur Lenormand, Philibert Lamaty, Frédéric Pinaud, Julien Bantreil, Xavier
Published in
Angewandte Chemie (International ed. in English)
Albeit mechanochemistry is a novel promising technology that give access to reactivity under solvent-free conditions, heating such reactions is sometimes compulsory to obtain satisfactory results in terms of conversion, selectivity and/or yield. In this work, we developed a novel approach using a dye that absorbs NIR photons and release the energy ...
Wu, Bin Meng, Haibing Chen, Xingbao Guo, Ying Jiang, Li Shi, Xiaofeng Zhu, Jiexin Long, Juncai Gao, Wenliang Zeng, Feng
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Published in
Angewandte Chemie (International ed. in English)
Nanographenes are among the fastest-growing materials used for the oxygen reduction reaction (ORR) thanks to their low cost, environmental friendliness, excellent electrical conductivity, and scalable synthesis. The perspective of replacing precious metal-based electrocatalysts with functionalized graphene is highly desirable for reducing costs in ...
Hu, Bangping Liu, Qinian Jiang, Yulan Huang, Yujie Ji, Huiquan Zhang, Jiqi Wang, Xia Shen, Xing-Can Chen, Hua
Published in
Angewandte Chemie (International ed. in English)
Hydrogen persulfide (H2S2) plays a significant role in redox biology and signal transduction; therefore, quantitative visualization of H2S2 in the deep tissue of living organisms is essential for obtaining reliable information about relevant pathophysiological processes directly. However, currently reported H2S2 probes are unsuitable for this purpos...
Bhoyare, Vivek W Sosa Carrizo, E Daiann Gandon, Vincent Patil, Nitin T
Published in
Angewandte Chemie (International ed. in English)
We recently reported the gold-catalyzed Heck and chain-walking reactions, which utilize migratory insertion, β-hydride elimination steps in a catalytic fashion. Budzelaar et al. in their correspondence state that these reactions proceed through gold-catalyzed alkene heteroarylation followed by acid-mediated elimination and cyclization sequence. In ...
Peng, Yong Rabeah, Jabor Junge, Henrik Beller, Matthias
Published in
Angewandte Chemie (International ed. in English)
Photocatalytic water splitting for hydrogen evolution is a highly topical subject in academic research and a promising approach for sustainable fuel production from solar energy. Due to the mismatched energy diagram of the photosensitizer (especially semiconductor-based materials where band-edge engineering is not trivial) and the redox potential o...
